Synthesis and some transformation ofN-allyl-N′-methoxy-andN-allyl-N′-tosyloxydiazeneN-oxides |
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| Authors: | O A Lukýanov N I Shlykova |
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| Institution: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp, 117913 Moscow, Russian Federation |
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| Abstract: | The first representatives ofN-2-alkenyl-N′-alkoxydiazeneN-oxides andN-2-alkenyl-N′-sulphonyloxydiazeneN-oxides have been synthesized. Some reactions of the double bond in these compounds have been studied. The possibility of
isomerization ofN-2-alkenyl-N′-alkoxydiazeneN-oxides toN-alk-1-enyl derivatives has been discovered.
See Ref. 1 and the references therein.
Translated fromIzvestiya Akademii Nauk, Seriya Khimicheskaya, No. 11, pp. 2262–2265, November, 1998. |
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| Keywords: | N-allyl-N′ -methoxydiazeneN-oxide N-allyl-N′ -tosyloxydiazeneN-oxide alkylation tosylation bromination isomerization 1 3-dipolar cycloaddition |
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