| Synthesis in solid state, structural regularity and reaction mechanism for [VS_4-Cu_n] clusters |
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| 引用本文： | 余秀芬,郑发鲲,黄锦顺. Synthesis in solid state, structural regularity and reaction mechanism for [VS_4-Cu_n] clusters[J]. 中国科学B辑(英文版), 1996, 0(4) |
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| 作者姓名： | 余秀芬 郑发鲲 黄锦顺 |
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| 作者单位： | Department of Chemistry，Fuzhou University，Fuzhou 350002，China，Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou 350002，China，Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou 350002，China |
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| 基金项目： | Project supported by the State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences |
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| 摘 要： | The reaction system (NH4)3VS4/CuCl/PPh3/Et4NBr afforded a series of [VS4-Cun] dusters with various core configurations in the solid state at low heating temperature. The structural regularity of [VS4-Cun] dusters and the influence of the CuCl:(NH4)3VS4 ratio as well as that of reaction temperature and time on the formation of duster core have been summarized. The reaction mechanism of forming V-Cu-S clusters has also been explored.
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Synthesis in solid state, structural regularity and reaction mechanism for [VS_4-Cu_n] clusters |
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| YU Xiufen. Synthesis in solid state, structural regularity and reaction mechanism for [VS_4-Cu_n] clusters[J]. Science in China(Chemistry), 1996, 0(4) |
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| Authors: | YU Xiufen |
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| Abstract: | The reaction system (NH4)3VS4/CuCl/PPh3/Et4NBr afforded a series of [VS4-Cun] dusters with various core configurations in the solid state at low heating temperature. The structural regularity of [VS4-Cun] dusters and the influence of the CuCl:(NH4)3VS4 ratio as well as that of reaction temperature and time on the formation of duster core have been summarized. The reaction mechanism of forming V-Cu-S clusters has also been explored. |
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| Keywords: | clusters vanadium cluster vanadium copper cluster. |
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