Some applications of the diels–alder reaction in organosilicon chemistry

A review of advances in the applications of the Diels–Alder reaction in organosilicon chemistry in our laboratory is presented. Using this reaction, we have synthesized a series of organosilicon monomers and polymers with polyphenyl groups and condensed rings and established a novel vulcanization system for silicone rubber. In addition, we discuss the influences of the large aromatic groups on the properties of the polymers.