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Nonadiabatic collision model calculations of ion-pair formation cross sections of Cs+O2→Cs++O
Authors:Zheng-Ting Cai  Yu-Guang Mu  Den G Cong-Hao
Abstract:This paper has improved Hickman's nonadiabatic collision model by substituting Hickman's constant velocity classical straight line trajectory approximation with the solution of motion equation mR=?dV(R)/dR, and has calculated the cross sections of ion-pair formation Cs+O2→Cs++O?2 with the improved nonadiabatic collision model (INCM). A comparison of our results with other theoretical and experimental results has been made.
Keywords:Ion-pair formation reaction  nonadiabatic collision model  two-state potential energy surface  quantum scattering theory  
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