| 聚酰胺的合成——N-羟基-5-降冰片烯-2,3-双甲酰亚胺的双活性酯与脂族二胺间在温和条件下的缩聚反应 |
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| 引用本文： | 陆承勋,刘佩刚,胡昌.聚酰胺的合成——N-羟基-5-降冰片烯-2,3-双甲酰亚胺的双活性酯与脂族二胺间在温和条件下的缩聚反应[J].高分子学报,1981,0(2):154-157. |
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| 作者姓名： | 陆承勋 刘佩刚 胡昌 |
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| 作者单位： | 北京大学化学系
(陆承勋，刘佩刚)，中国科学院化学研究所(胡昌) |
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| 摘 要： | <正> 在合成聚酰胺的研究中,关于由N-羟基化合物O,O′-双酰基衍生物与二元胺在温和条件下合成聚酰胺的报道较少。Overberger及ebenda首先研究了N-羟基丁二酰亚胺的双活性酯及N-羟基邻苯二甲酰亚胺的双活性酯与派嗪间的缩聚反应。Ueda、Imai等则报道了另两类活性双酯,如1-羟基苯并三氮唑的双活性酯及O,O′-间苯二甲酰双肟与二元胺间的缩聚合成聚酰胺的结果。
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| 收稿时间： | 1980-08-26 |
SYNTHESIS OF POLYAMIDES FROM ACTIVE DIESTER OF N-HYDROXY-5-NORBORNENE-2,3-DICARBOXIMIDE AND DIAMINES UNDER MILD CONDITIONS |
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| Lu Cheng-xun,Liu Peig-ang,Hu Chang.SYNTHESIS OF POLYAMIDES FROM ACTIVE DIESTER OF N-HYDROXY-5-NORBORNENE-2,3-DICARBOXIMIDE AND DIAMINES UNDER MILD CONDITIONS[J].Acta Polymerica Sinica,1981,0(2):154-157. |
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| Authors: | Lu Cheng-xun Liu Peig-ang Hu Chang |
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| Institution: | Department of Chemistry; Beijing University, Institute of Chemistry; Academia Siniea |
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| Abstract: | A new route to polyamides -was established on the polycondensation of a new typical active diester, active diester of N-hydroxy-5-norbornene-2,3-dicarboximide such as N,N'-(isophthaloyldioxy) bis(5-norbornene-2,3-dicarboximide) and N,N'-(terephthaloyl-dioxy) bis (5-norbornene-2,3-dicarboximide) with diamines including ethylenediamine and hexamethylenediamine. The polycondensation occurred at room temperature without added catalyst in solution. |
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