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Potassium selenocyanate as an efficient selenium source in C-Se cross-coupling catalyzed by copper iodide in water
Authors:A Vijay KumarV Prakash Reddy  C Suresh ReddyK Rama Rao
Institution:a Organic Chemistry Divison-I, Indian Institute of Chemical Technology, Hyderabad 500 607, India
b Department of Chemistry, Sri Venkateswara University, Tirupati, India
Abstract:An efficient and conceptually new protocol for C-Se cross coupling of potassium selenocyanate with aryl halides via copper-catalyzed cascade reaction has been developed in water. Utilizing this protocol, a variety of aryl and heteroaryl halides were reacted with potassium selenocyanate to afford the corresponding diaryl selenides in moderate to good yields.
Keywords:Aryl halides  Potassium selenocyanate  Diaryl selenides  Cross-coupling  Copper iodide  Water
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