An alternative approach for the synthesis of aryl-alkyl tellurides: reaction of aryl iodides with metal alkyltellurolates promoted by CuI |
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Authors: | Má rcio S. Silva,Joã o V. Comasseto |
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Affiliation: | Instituto de Química, Universidade de São Paulo, Av. Prof. Lineu Prestes, 748, Caixa Postal 26077, 05508-000 São Paulo, SP, Brazil |
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Abstract: | Aryl iodides react with metal organotellurolates in tetrahydrofuran/dimethylformamide in the presence of CuI (5 mol %) or CuI (5 mol %) and 1,10-phenanthroline (10 mol %) to afford the corresponding aryl-alkyl tellurides in good yields. |
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Keywords: | Organotellurolate Coupling reaction Aryl-alkyl telluride Copper iodide Aryl iodide |
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