Aromatics to polyquinanes: A general method for the construction of tricyclo[6.3.0.0]-and tricyclo[6.3.0.0]undecanes |
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| Authors: | PJohn Biju GSRSubba Rao |
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| Institution: | aDepartment of Organic Chemistry, Indian Institute of Science, Bangalore 560 012, India |
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| Abstract: | The conversion of aromatic compounds to linear and angular triquinanes is described and involves a 5-exo-trig-allyl radical cyclization as the key reaction for constructing the strained ketones 9 and 18, which are then transformed into the quinanes 12 and 23, respectively. |
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