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The Orbitrap mass analyzer with direct ion injection interfaced to a laser desorption/ionization ion source
Authors:A. A. Makarov  A. A. Grechnikov  S. M. Nikiforov  O. A. Tyutyunnik  E. V. Denisov
Affiliation:1. Prokhorov General Physics Institute, Russian Academy of Sciences, ul. Vavilova 38, Moscow, 119991, Russia
3. ThermoFisher Scientific (Bremen) GmbH, Hanna-Kunath Str. 11, Bremen, 28199, Germany
2. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, ul. Kosygina 19, Moscow, 119991, Russia
Abstract:The results of a study on interfacing an Orbitrap mass analyzer with direct ion injection to a surface assisted laser desorption/ionization (SALDI) ion source are presented. Osmium complexes with 8-mercaptoquinoline were studied. Titanium oxide thin films prepared by electron beam evaporation were found an effective emitter of the ions of the test complexes. It was demonstrated that interfacing the Orbitrap mass analyzer to a SALDI source can significantly improve the analytical performance of this method in comparison to a typical combination of SALDI/time-of-flight mass spectrometer.
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