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Synthesis,Crystal Structure and Luminescence of [Ag(PPh3)2(H2TMT)] |
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| Authors: | Yong‐Qin Wei Ke‐Chen Wu Bo‐Tao Zhuang Zhang‐Feng Zhou Ming‐Xin Zhang Cai‐Ping Liu |
| Abstract: | The silver complex Ag(PPh3)2(H2TMT) ( 1 )(H3TMT = 2,4,6‐trimercapto‐1,3,5‐triazine) has been synthesized and characterized. The ligand trimercaptotriazine exhibits a novel coordination mode and the complex shows a special hydrogen bonding linkage in the crystal packing. The colorless crystals of 1 exhibit broad emission in the visible region at room temperature. TDDFT calculation indicated that the π–π attraction is crucial for fluorescence of the title complex. |
| Keywords: | Silver Trimercaptotriazine Crystal structure Luminescence spectra π – π imteraction |