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π–π Stacking‐Interlinked Molecular Squares with Hepta‐Coordinated Cadmium(II) Corners, [Cd(DMAP)3(NO2)2]·0.5H2O |
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| Authors: | Farzin Marandi Ali Akbar Soudi Ali Morsali Rhett Kempe |
| Abstract: | The single crystal X‐ray analysis data of the new hepta‐coordinate cadmium(II) complex of N,N‐dimethyl‐N‐(4‐pyridyl)amine (DMPA), Cd(DMPA)3(NO2)2]·0.5H2O, shows that the coordination environment around the CdII is pentagonal bipyramidal. Furthermore, self‐assembly of this complex as molecular squares that interlink via π–π stacking interactions is observed. This network contains voids that are filled by water molecules. |
| Keywords: | Cadmium N N‐dimethyl‐N‐(4‐pyridyl)amine π – π stacking Molecular squares |