Synthesis of a Stable Biphenyl‐Bis(carbene) and ‐Bis(silylene) [M{(NCH2But)2C6H3‐3,4}]2 (M = C or Si) |
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Authors: | Barbara Gehrhus Peter B Hitchcock Michael F Lappert |
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Abstract: | Treatment of the biphenyl derivative S=C{(NCH2But)2C6H3‐3,4}]2 or Cl2Si{(NCH2But)2C6H3‐3,4}]2 with C8K afforded the new bis(carbene) 1 or the first bis(silylene) 2 , respectively. The X‐ray structure of 2 is presented. |
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Keywords: | Carbene Silylene |
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