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TAS‐Indolid und TAS‐Carbazolid: Strukturen von [TAS]+[IndHInd]− und [TAS]+[Carb]−·½CarbH |
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| Authors: | Marco Müller Enno Lork Rüdiger Mews |
| Abstract: | TAS Indolide and TAS Carbazolide: Structures of TAS]+IndHInd]? and TAS]+Carb]?·½CarbH From the reaction of TAS‐fluoride (Me2N)3S]+Me3SiF2]? with trimethylsilyl‐indole and trimethylsilyl‐carbazole TAS‐indolide and TAS‐carbazolide are formed. During crystallisation partially protonation to indole and carbazole occurs, resulting in the formation of TAS]+IndHInd]? ( 3a ) and TAS]+Carb]?·½CarbH ( 5a ) according to X‐ray analysis. |
| Keywords: | Sulfonium salts Crystal structures Indolide Carbazolide |