(1) Department of Chemistry, McGill University, H3A 2K6 Montreal, Canada
Abstract:
Measurements of the partial molar volumes in water at 25°C of the mono-and dihydrochlorides of the ,-diaminoalkanes, up to a chain length of 10 carbon atoms, are reported. Volumes of ionization have been determined and the electrostriction of the solvent calculated. Effects of the substituents are felt up to the -carbon atom, but thereafter are only very weak or nonexistent.