Compensation effect in solid-state reactions. Thermolysis of one substance under differing experimental conditions |
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| Authors: | A. V. Nikolaev V. A. Logvinenko |
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| Affiliation: | (1) Sibirian Department of the Academy of Sciences of the U.S.S.R., Institute of Inorganic Chemistry, Novosibirsk |
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| Abstract: | The compensation effect (lgZ=aE+wb) appearing at the thermolysis of one substance under different experimental conditions is discussed. The compensation effect of one and the same substance has no other physical meaning except the simple confirmation of the analytical relationship between lgZ andE that follows from the Arrhenius equation, and of the impossibility to determineZ from any independent experiment. Values of the coefficienta can not be the measure of the ruptured bond strength.
                   (lgZ= +b),         .     , lgZ E (  ) Z .  a .
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