| 新型含氟聚芳醚酮的合成与表征 |
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| 引用本文： | 刘佰军,陈春海,呼微,孙辉,赵爽,姜振华,张万金,吴忠文. 新型含氟聚芳醚酮的合成与表征[J]. 高等学校化学学报, 2002, 23(2): 321-323 |
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| 作者姓名： | 刘佰军 陈春海 呼微 孙辉 赵爽 姜振华 张万金 吴忠文 |
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| 作者单位： | 吉林大学化学学院,长春,130023 |
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| 基金项目： | 国防科工委国防基金 (批准号 :99J12 .1.2 .130 1)资助 |
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| 摘 要： | 聚芳醚酮具有很高的热稳定性和优良的电性能及机械性能 ,已经被广泛应用于宇航、电子及核能等高技术领域 [1] .氟元素的引入可以降低材料介电常数、折光指数和吸水率 ,提高热稳定性、溶解性和阻燃性 ,增加材料透明度 ,使这类聚合物在光电子、光学和微电子等应用领域的研究倍受关注 [2～ 4 ] .本文在合成含三氟甲基苯侧基的聚芳醚酮 [5] 的基础上 ,设计并合成了新型的含氟量更高的单体和聚合物 ,并对其性能进行了初步研究 .1 实验部分1 .1 试剂与仪器 [3,5 -二 (三氟甲基 ) ]苯代对苯醌 (自制 ) ;锌粉 ,A.R.级 ,天津化学试剂一厂产品 ;…
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| 关 键 词： | 聚芳醚酮 溶解性 含氟聚合物 合成 表征 三氟甲基苯 性能 |
| 文章编号： | 0251-0790(2002)02-0321-03 |
Synthesis and Characterization of Novel Fluorine-containingPoly(aryl ether ketone)s |
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| LIU Bai Jun ,CHEN Chun Hai,HU Wei,SUN Hui,ZHAO Shuang JIANG Zhen Hua,ZHANG Wan Jin,WU Zhong Wen. Synthesis and Characterization of Novel Fluorine-containingPoly(aryl ether ketone)s[J]. Chemical Research In Chinese Universities, 2002, 23(2): 321-323 |
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| Authors: | LIU Bai Jun CHEN Chun Hai HU Wei SUN Hui ZHAO Shuang JIANG Zhen Hua ZHANG Wan Jin WU Zhong Wen |
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| Affiliation: | LIU Bai Jun *,CHEN Chun Hai,HU Wei,SUN Hui,ZHAO Shuang JIANG Zhen Hua,ZHANG Wan Jin,WU Zhong Wen |
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| Abstract: | A kind of highly fluorinated bisphenol monomer was synthesized. It was characterized by FTIR, 1H NMR and MS. 6F PEEK and 6F PEEKK were prepared via aromatic nucleophilic substitution, based on [3,5 di(trifluoromethyl)] phenylhydroquinone and difluoro monomers. The T gs of 6F PEEK and 6F PEEKK are 423 and 436 K, respectively. The 6F polymers exhibit a high thermal stability and good solubility. The flexible, creasable and transparent thin films were easily obtained by compression moulding and solution casting. |
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| Keywords: | Poly(aryl ether ketone)s Solubility Fluorine containing polymers |
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