| 羧基苯偶氮基杯[8]芳烃衍生物的合成及表征 |
| |
| 引用本文： | 刘爱林,傅崇岗,张立云,赵艳芳. 羧基苯偶氮基杯[8]芳烃衍生物的合成及表征[J]. 合成化学, 2003, 11(1): 72-75 |
| |
| 作者姓名： | 刘爱林 傅崇岗 张立云 赵艳芳 |
| |
| 作者单位： | 聊城大学化学化工学院,山东,聊城,252059 |
| |
| 基金项目： | 山东省青年科学基金 ( Q99B11)，教育部“高等学校骨干教师资助计划”项目 |
| |
| 摘 要： | 以邻、间或对氨基苯甲酸和杯[8]芳烃为原料，经重氮化一偶联反应合成了新型有色邻、间或对羰基苯偶氮基杯[8]芳烃，产物的结构经元素分析，IR，UV－Vis和1H NMR表征，并研究了它们的生色原理和光谱性能，实验结果表明它们是一类新型指示剂和具有新型配位空腔的主体分子。
|
| 关 键 词： | 表征 氨基苯甲酸 杯[8]芳烃 羧基苯偶氮基杯[8]芳烃衍生物 合成 结构 |
| 文章编号： | 1005-1511(2003)01-072-04 |
| 修稿时间： | 2002-06-18 |
The Synthesis and Characterization of Carboxylazocalix[8]arene Derivatives |
| |
| LIU Ai-lin,FU Chong-gang,ZHANG Li-yun,ZHAO Yan-fang. The Synthesis and Characterization of Carboxylazocalix[8]arene Derivatives[J]. Chinese Journal of Synthetic Chemistry, 2003, 11(1): 72-75 |
| |
| Authors: | LIU Ai-lin FU Chong-gang ZHANG Li-yun ZHAO Yan-fang |
| |
| Abstract: | The synthesis of new chromogenic (o- or m-)p-carboxylazocalixarene derivatives through the coupling of diazotized (o- or m-)p-aminobenzene carboxylic acid and calixarene is described. Their structures were confirmed by elemental analysis, IR and 1H NMR. Their chromogenic properties and UV-Vis absorption spectra were investigated under different pH conditions. Experimental results show that the synthesized derivatives can be used as new indicators and host moleculars. |
| |
| Keywords: | aminobenzene carboxylic acid calixarene carboxylazocalixarene derivatives synthesis |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
