Luminescence of antimony(III) halide complexes with aniline |
| |
Authors: | T. V. Sedakova A. G. Mirochnik V. E. Karasev |
| |
Affiliation: | (1) Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia |
| |
Abstract: | The antimony(III) chloride and bromide complexes with aniline, (C6H5NH3)2SbCl5·(C6H5NH3)Cl·H2O (I) and (C6H5NH3)2SbBr5 (II), were synthesized, and their spectral luminescence properties were studied. An interesting peculiarity of I and II is the possibility of selective excitation of luminescence in the π system of the (C6H5NH3)+ outer sphere anilinium cation and intrinsic luminescence of the s 2 ion. The population scheme for the luminescent antimony 3 P 1 level in I and II is discussed using the luminescence, UV, and photoelectron spectroscopy data. Original Russian Text ? T.V. Sedakova, A.G. Mirochnik, V.E. Karasev, 2009, published in Zhurnal Fizicheskoi Khimii, 2009, Vol. 83, No. 2, pp. 380–382. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|