Novel Ca-doped CePO4 supported ruthenium catalyst with superior catalytic performance for aerobic oxidation of alcohols |
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Authors: | Zhang Yanjie Wang Junhu Zhang Tao |
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Institution: | State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China. |
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Abstract: | Ca-doped cerium phosphate (CeCaPO(4)) has been newly developed and successfully used as catalyst support with superior ion-exchanged property and oxygen activation ability. Ru(3+) exchanged CeCaPO(4) is identified as an efficient catalyst for aerobic oxidation of alcohols with the highest TOF (~408 h(-1)) reported so far on supported Ru catalysts. |
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