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Ternary composites of multi-wall carbon nanotubes,polyaniline, and noble-metal nanoparticles for potential applications in electrocatalysis
Authors:Irina Sapurina  Jaroslav Stejskal
Affiliation:(1) Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, 199004, Russian Federation;(2) Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, 162 06 Prague 6, Czech Republic
Abstract:Multi-wall carbon nanotubes were coated with a conducting polymer, polyaniline phosphotungstate. Such composite structures have mixed electronic and proton conductivity, high surface area and porosity. These materials were decorated with catalytically-active noble metals — Pt, Pd, and Rh. Metal nanoparticles were uniformly distributed in the polymer matrix. Such ternary composites can be considered as electrode materials in sensors, electrolysers, supercapacitors, and especially in low-temperature fuel cells with a proton-conducting polymer membrane.
Keywords:conducting polymer  polyaniline  proton conductivity  noble metals  nanoparticles  carbon nanotubes
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