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Effect of the Nature of the Oxidizing Agent on Conversion of Finely Dispersed Carbon on Binary Oxide Catalysts
Authors:S. A. Solov'ev  Ya. P. Kurilets  S. N. Orlik
Affiliation:(1) L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky 31, 03028 Kyiv, Ukraine
Abstract:We have studied the process of catalytic oxidation of finely dispersed carbon on the surface of the designed soot filters, prepared by successive deposition of a second support (γ-Al2O3) and a catalytic coating (CuCr2O4 or CuCo2O4) on ceramic honeycomb monoliths of synthetic cordierite, using different oxidizing agents: O2, O3, NO, NO2, H2O. Using ozone as the oxidation initiator allows us to solve the problem of comprehensive purification of automobile exhaust gases at fairly low temperatures (“cold start”). __________ Translated from Teoreticheskaya i Eksperimental'naya Khimiya, Vol. 41, No. 5, pp. 307–312, September–October, 2005.
Keywords:soot filter  second support  catalyst  complex oxides of transition metals  oxidizing agent  ozone
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