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Variable temperature solution and cp-mas C NMR of [Mo(CO)3(diglyme)]. Displacement of diglyme by solvents at subambient temperatures |
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| Authors: | George W. Wagner and Brian E. Hanson |
| Affiliation: | Chemistry Department, Virginia Polytechnic Institute and State University, Blacksburg, VA 24061, U.S.A. |
| Abstract: | Variable temperature solution 13C NMR of [Mo(CO)3(diglyme)] shows that the chelating diglyme ligand is displaced by the monodentate solvents acetone, methanol and ethanol at low temperature. Free and coordinated solvent are observed at low temperature while at ambient temperature rapid exchange prevents the observation of coordinated solvent. |
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