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稀土Er掺杂ZnF2: PbF4的能量上转换
引用本文:袁放成. 稀土Er掺杂ZnF2: PbF4的能量上转换[J]. 光谱学与光谱分析, 2005, 25(8): 1187-1189
作者姓名:袁放成
作者单位:泉州师范学院物理系,福建,泉州,362000
基金项目:福建省泉州市科技局资助项目(Z200234)
摘    要:在氟化锌(ZnF2)或氟化锆(ZrF4),氟化铅(PbF4)等基质材料中加入不等量的Er3 及微量Yb3 离子,在特定的条件下制作成能量上转换材料。样品在980nm的红外光激发下发出较强的多波段的可见光,且肉眼可见。由实验样品分析了稀土Er3 上转换可见光各波段的谱线,给出了能级跃迁机制,并根据稀土Er3 摩尔浓度不同的样品其上转换发光强度的不同,分析了掺入稀土的浓度对能量上转换效率的影响。

关 键 词:能量上转换  Er3+  Yb3+  荧光光谱
文章编号:1000-0593(2005)08-1187-03
收稿时间:2004-11-23
修稿时间:2005-05-08

Energy Upconversion from Rare Earth Er Doped ZnF2: PbF4
YUAN Fang-cheng. Energy Upconversion from Rare Earth Er Doped ZnF2: PbF4[J]. Spectroscopy and Spectral Analysis, 2005, 25(8): 1187-1189
Authors:YUAN Fang-cheng
Affiliation:Department of Physics, Quanzhou Normal University, Quanzhou 362000, China.
Abstract:Energy-upconversion meterials were produced by adding Er~(3 ) and Yb~(3 ) ions to lead fluoride, zirconium fluoride or zinc fluoride under specific conditions. Under the excitation of infrared light at 980 nm, the material samples emit relatively strong multi-band visible light, which comes into view by naked eyes. Based on the experiment, the multi-band visible spectral lines of Er~(3 ) were analyzed, the energy level transition mechanism was given, and the effect of rare earth doping concentration on the energy upconversion efficiency was analyzed, according to the different upconversion light emitting intensity from samples with different Er~(3 ) mol concentrations.
Keywords:Energy up-conversion  Er~(3 )  Yb~(3 )  Fluorescence spectrum
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