| MCM-41表面新戊基锆和氧化锆的制备 |
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| 引用本文： | 王绪绪,赵慧霞,付贤智.MCM-41表面新戊基锆和氧化锆的制备[J].无机化学学报,2001,17(1):83-88. |
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| 作者姓名： | 王绪绪 赵慧霞 付贤智 |
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| 作者单位： | 1. 福州大学化肥催化剂国家工程研究中心,
2. 福州大学化学系, |
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| 摘 要： | 首次在高真空系统中利用ＺrCH2C(CH3)3]4与表面羟基的反应把－ＺrCH2C(CH3)3]2基团接枝在介孔硅胶ＭＣＭ－４１的表面上，经进一步氧化和水解得到了表面富锆ＭＣＭ－４１材料，采用元素分析、ＦＴＩＲ、固态ＮＭＲ、Ｘ射线粉末射及吡啶化学吸附等分别表征了材料的组成及性质，初步研究表明接枝法制备的ＺrMCM-41比水热法合成的样品有更好的吸附和催化性能。
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| 关 键 词： | 四新戊基锆 MCM－41 分子筛 化学接枝 制备 催化性能 吸附性能 |
| 收稿时间： | 2000/7/23 0:00:00 |
| 修稿时间： | 2000年7月23日 |
Preparation of MCM-41 Surface Neopentylzirconium and Zirconia |
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| WANG Xu-Xu,ZHAO Hui-Xia and FU Xian-Zhi.Preparation of MCM-41 Surface Neopentylzirconium and Zirconia[J].Chinese Journal of Inorganic Chemistry,2001,17(1):83-88. |
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| Authors: | WANG Xu-Xu ZHAO Hui-Xia and FU Xian-Zhi |
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| Institution: | WANG Xu-Xu1 ZHAO Hui-Xia2 FU Xian-Zhi1 |
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| Abstract: | -ZrCH2C(CH3)3]2 groups were grafted on surface of MCM-41 by a reaction with the surface hydroxyls in a high vacuum system for the first time. Hydrolysis or oxidation of the grafted groups resulted in richness of zirconium on the surface of MCM-41. The properties and composition of the materials were characterized by elemental analysis, FTIR, solid-state NMR, XRD and pyridine adsorption.The results showed that the catalytic and adsorptive performance of the grafted ZrMCM-41 was better than that of the hydrothermally synthesized ZrMCM-41. |
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| Keywords: | ZrMCM-41 tetraneopentylzirconium chemical grafting preparation |
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