Curing theory of Af- Ag type free radical polymerization (III) |
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| Authors: | Haijun Wang Xinwu Ba Min Zhao Zesheng Li |
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| Affiliation: | (1) Department of Chemistry, Hebei University, 071002 Baoding, China;(2) Institute of Theoretical Chemistry and State Key Laboratory of Theoretical and Computational Chemistry, Jilin University, 130023 Changchun, China |
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| Abstract: | Evaluation of defects in the polymer network is important to characterize the polymer materials, in which there always exist the defects that affect the physical and chemical properties of polymer network. Taking Af- Ag type nonlinear free radical polymerization as an example, one type of defects called dangling loops in the gel network is investigated by means of the statistical theory of polymeric reactions. The number of dangling loops and the probability of its formation are obtained by analyzing the polymer network structure in detail. |
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| Keywords: | free radical polymerization curing theory network defects |
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