Studies of vanadium catalysts for sulfur dioxide oxidation by51V-NMR |
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| Authors: | V M Mastikhin O B Lapina V F Lyakhova and L G Simonova |
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| Institution: | (1) Institute of Catalysis, Novosibirsk, USSR |
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| Abstract: | Studies of the51V-NMR spectra of a series of industrial catalysts and systems modelling the active catalyst component indicate that the catalyst composition depends on the preparation method and during thermal treatment the support interacts with the active component. The local environment of vanadium is being formed in the process of catalytic reactions.
                 51V     ,  -I-4,   ,       : KVO3, KVO3–SiO2, KVO3–K2SO4 ,      , .    .
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