Über Chalkogenolate. LVII. Untersuchungen über Thioameisensäuren 5. Darstellung und Eigenschaften von Estern der Dithioameisensäure |
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| Authors: | R. Engler,G. Gattow,M. Dr ger |
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| Affiliation: | R. Engler,G. Gattow,M. Dräger |
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| Abstract: | Esters of the trimeric dithioformic acid [HCS(SR)]3 were prepared by interaction of K[HCS2] with alkyl iodides (R = CH3, C2H5). Orthoesters HC(SR)3 and di-orthoesters of the monomeric dithioformic acid were formed by reaction of formic acid with thioles (RSH mit R = CH3, C2H5, CH2C6H5) or dithioles (HS? (CH2)n? SH with n = 2, 3,4). The prepared compound were characterised by different methods. |
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