Influence of hydrostatic pressure on the phase transition in the complex antifluorites and hexammines: Rigid-sphere model interpretation |
| |
| Authors: | M Krupski |
| |
| Institution: | Institute of Molecular Physics, Polish Academy of Sciences , Smoluchowskiego 17/19, 60–179, Poznań, Poland |
| |
| Abstract: | Abstract The pressure coefficient of the phase transition temperature Tc, dTc/dp = -(11+-1) K/GPa, has been determined for Ni (NH3)6Cl2 using a new high pressure and low temperature probe. The relations between Tc and dTc/dp were determined for antifluorite K2MCl6 compounds and hexammines applying the rigid-sphere model. |
| |
| Keywords: | Phase transition hydrostatic pressure antifluorites hexammines rigid-sphere model |
|
|
