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Equation of state of turbostratic boron nitride
Authors:Vladimir L. Solozhenko  Elena G. Solozhenko
Affiliation:Institute for Superhard Materials of the National Academy of Sciences of Ukraine , 2, Avtozavodrkaya St., Kiev, 04074, Ukraine
Abstract:Abstract

The lattice parameters of turbostratic boron nitride (tBN) have been measured to 6.1 GPa at room temperature using energy-dispersive powder diffraction with synchrotron radiation. A fit to the experimental p-V data using Birch-Murnaghan equation of state gives values of the tBN bulk modulus 17.5(8) GPa and its pressure derivative ll.4(5). These values point to significantly higher compressibility of turbostratic BN as compared to three-dimensionally ordered graphite-like hexagonal and rhombohedral boron nitride.
Keywords:Graphite-like boron nitride  Turbostratic stacking faults  High pressure  Compressibility
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