Zur Wechselwirkung einiger Übergangsmetallhalogenide mit o-Mercaptophenol |
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| Authors: | K Andr W Rollka |
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| Institution: | K. Andrä,W. Rollka |
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| Abstract: | The interaction of some transition metal halides with o-mercaptophenol o-Mercaptophenol reacts with WCl6, TiCl4, ZrCl4, NbCl5 and TaCl5 giving the corresponding tris-chelat-komplexe W(C6H4OS)3, H2M(C6H4OS)3] (M = Ti, Zr), HM(C6H4OS)3] (M = Nb, Ta). (C5H5)2TiCl2 and (C5H5)2ZrBr2give in presence of triethylamine the compounds (C5H5)2M(C6H4OS) (M = Ti, Zr). By reaction of nickel(II) acetyl-acetonate with o-mercaptophenol the polymeric octahedral complex nickel-bis-(o-hydroxy-thiophenolate) results. |
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