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Electrical conductivity anisotropy in alkali feldspar at high temperature and pressure
Authors:Duojun Wang  Yingjie Yu  Yongsheng Zhou
Affiliation:1. Key Laboratory of Computational Geodynamics, College of Earth Sciences, University of Chinese Academy of Sciences, Beijing 100049, Chinaduojunwang@ucas.ac.cn;3. Key Laboratory of Computational Geodynamics, College of Earth Sciences, University of Chinese Academy of Sciences, Beijing 100049, China;4. Key Laboratory of Earthquake Dynamics, Institute of Geology, China Earthquake Administration, Beijing 100029, China
Abstract:The electrical conductivity of alkali feldspar along different orientations was determined at 1.0 GPa and at temperatures of 823–1286 K in a cubic anvil apparatus using alternating current impedance spectroscopy. Impedance arcs representing crystal conductivity occur in the frequency range of ~103–106 Hz. The electrical conductivity of alkali feldspar increases with increasing temperature. The highest electrical conductivities in alkali feldspars were measured along the a-axis, with somewhat lower conductivities along the b-axis, and the lowest conductivities along the c-axis, suggesting minor anisotropy. The activation enthalpies ranged from 100 to 110 kJ/mol. The anisotropic results were combined to yield an isotropic model with an activation enthalpy of 102 kJ/mol. By comparing these results with previous results, we suggest that the dominating charge carriers for alkali feldspars are alkali ions. The minor anisotropy in conductivity for alkali feldspar may not account for the anisotropy of the crust.
Keywords:electrical conductivity  alkali feldspar  anisotropy
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