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Phase diagram of aqueous solution at high pressure and low temperature
Authors:J. M. Chourot  A. Le Bail  D. Chevalier
Affiliation:1. CEMAGREF-GPAN-BP44, 92160, ANTONY cedex, France;2. ENITIAA-LGPA-BP82225, F-44322, Nantes cedex 3, France
Abstract:Abstract

This paper presents a constant mass high pressure isothermal calorimeter and describes the range of applications that this type of equipment can deal with. As an example, the thermophysical properties of an aqueous solution of MgSO4 at low temperature and at high pressure have been investigated. The main results showed that the phase change heat of the solution decreased with increasing pressure and the phase change temperature of the eutectic concentration was depressed under high pressure. Those changes could be related to the MgSO4 solubility and to water latent heat changes.
Keywords:Key words:Keywords: High pressure  aqueous solution  phase change  calorimetry
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