Indirect polarographic determination of stability constants |
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Authors: | R Sundaresan A K Sundaram |
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Institution: | 1. Analytical Chemistry Division, Bhabha Atomic Research Centre, Trombay, 400085, Bombay
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Abstract: | Zinc, complexes of glycollic and lactic acids were studied by an indirect polarographic method using cadmium as the indicator ion. The half-wave potentials of cadmium complexes shift to more positive values in the presence of zinc. From this shift, the formation function, -n, for zinc was obtained as a function of ligand concentration and the stability constants were calculated. |
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