New complex of zinc(II) with schiff base derived from furaldehyde and diethylenetriamine: Synthesis and crystal structure |
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| Authors: | W Wang F X Zhang J Li W B Hu |
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| Institution: | (1) Department of General and Coordination Chemistry, Faculty of Chemistry, Maria Curie-Skłodowska University, M.C. Skłodowskiej Sq. 2, 20-031 Lublin, Poland |
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| Abstract: | A new zinc(II) complex, ZnLCl2 (L = N,N′-bis(furaldehyde)diethylenetriamine), was synthesized and characterized by X-ray crystallography analysis. The crystal belongs to the triclinic crystal system, space group \(P\bar 1\), with cell parameters a = 7.365(5), b = 13.591(9), c = 17.627(11) Å, α = 94.386(12)°, β = 93.643(11)°, γ = 91.535(10)°, Z = 4, R 1 = 0.0478, and wR 2 = 0.0618. The coordination geometry around Zn(II) is a distorted tetrahedron containing one bidenate N,N′-bis(furaldehyde)diethylenetriamine ligand and two Cl? ions. |
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