Nucleophilic substitution in ethyl fluorosulfonoxydifluoroacetate |
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Authors: | I. L. Knunyants F. M. Mukhametshin L. S. German N. I. Delyagina G. G. Korovushkin |
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Affiliation: | (1) A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow |
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Abstract: | Conclusions Ethyl fluorosulfonoxydifluoroacetate undergoes nucleophilic replacement with the formation of derivatives of difluoroacetic acid. The reaction with fluoride anion mainly features cleavage of the S-O bond leading to the acid fluoride of the monoethyl ester of oxalic acid.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1435–1437, June, 1985. |
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