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Nucleophilic substitution in ethyl fluorosulfonoxydifluoroacetate
Authors:I L Knunyants  F M Mukhametshin  L S German  N I Delyagina  G G Korovushkin
Institution:(1) A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow
Abstract:Conclusions Ethyl fluorosulfonoxydifluoroacetate undergoes nucleophilic replacement with the formation of derivatives of difluoroacetic acid. The reaction with fluoride anion mainly features cleavage of the S-O bond leading to the acid fluoride of the monoethyl ester of oxalic acid.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1435–1437, June, 1985.
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