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The solubility parameters of metal acetylacetonates
Affiliation:1. Department of Chemistry and Biochemistry, Laurentian University, Sudbury, Ontario P3E 2C6, Canada;2. Department of Chemistry, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada;3. School of Cellular and Molecular Medicine, University of Bristol, Medical Sciences Building, Bristol BS8 1TD, United Kingdom
Abstract:Solubility parameters for Be(acac)2 and Th(acac)4 calculated from viscosity measurements on dilute solutions in benzene at 25.0°C have been compared with data for tris-acetylacetonates of Al, Cr, Mn, Fe and Co. In non-polar solvents the value does not vary much with the nature of the metal (average δ2 = 9.4 ± 0.4) nor do the molar volumes, which can be calculated from Vm = 90.5n ± 5%.
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