Characterisation of some polyamino complexes of Fe(II) and Fe(III) imides |
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| Affiliation: | 1. Department of Chemistry, University of Hawai‘i at Mānoa, 2545 McCarthy Mall, Honolulu, HI 96822, United States;2. Department of Chemistry, Allegheny College, 520 N. Main Street, Meadville, PA 16335, United States;3. Department of Chemistry, University of California, 9500 Gilman Drive, La Jolla, San Diego, CA 92093, United States;4. INFIQC, CONICET and Departamento de Química Teórica y Computacional, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Ciudad Universitaria, Córdoba, 5000 Argentina;5. Department of Chemistry, University of North Florida, 1, UNF Drive, Jacksonville, FL 32224, United States;6. Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716, United States |
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| Abstract: | Complexes of the types [Fe(imide)2(Am)2] and [Fe(imide)3(Am)(H2O)](imide = deprotonated malonimide and phthalimide; Am = dipyridyl and o-phenanthroline) have been prepared and characterised on the basis of IR, electronic spectra, conductance, magnetic and Mössbauer studies. The bonding powers of phthalimide and malonimide are almost the same and all the complexes have a distorted octahedral structure. |
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