摘 要: | This paper reports the determination of stability constants for complexes of Cd(Ⅱ)with Gly,Ala,Val,Asp,Gly—Asp,Asp Gly,Gly—Gly and Gly—Gly—Gly using both micro—pH—metric titra-tions and the application of convolution—deconvolution cyclic voltammetry at 25℃ and I=0.10 mol·dm~(-3)(KNO_3).Stability constants were calculated from pH—metric data using the SUPERQUAD com-puter program and cyclic voltammograms were collected,stored and manipulated using the EG and GCONDECON 300 software.A considerably larger ligand:metal ratio(e,g.50:1)was possible usingvoltammetry.Evaluation of results from the two techniques suggests that stability constants for thespeciesCdL_2]andCdL_3]are reliable when calculated fromvoltammetry while those forCdL]are morereliable when determined by pH-metric titration.
|