Highly diastereo- and enantioselective reagents for aldehyde crotylation |
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| Authors: | Hackman Blaine M Lombardi Pamela J Leighton James L |
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| Affiliation: | Department of Chemistry, Columbia University, New York, New York 10027, USA. |
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| Abstract: | Two new, crystalline solid, storable, and highly enantioselective reagents for aldehyde crotylation have been developed. Both (cis and trans) crotylsilane reagents are easily prepared in bulk, require trivial reaction conditions, and provide the homoallylic alcohol products with near diastereo- and enantiospecificity in many cases. |
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