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Solvent-controlled regioselectivity in the ortho-palladation of benzylamines and intramolecular exchange in cyclopalladated ligands |
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| Authors: | A D Ryabov V A Polyakov I K Talebarovskaya V A Katkova A K Yatsimirskii I V Berezin |
| Institution: | (1) M. V. Lomonosov Moscow State University, USSR |
| Abstract: | Conclusions Cyclometallation of 1-(3 ,4-dimethoxyphenyl)-2-methyl-3-(4-nitrophenyl)-2-azapropane upon treatment with Pd(II) acetate occurs at the electron rich dimethoxy-substituted aromatic ring in CHCl3 solution, and at the electron poor nitrophenyl ring in AcOH solution.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 175–181, January, 1988. |
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