Anodic properties of diarylethene derivatives having organometallic piano-stool tags |
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| Authors: | Wu Kan Top Siden Hillard Elizabeth A Jaouen Gérard Geiger William E |
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| Affiliation: | Department of Chemistry, University of Vermont, Burlington, VT 05405, USA. |
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| Abstract: | The half-sandwich tamoxifen derivative, Mn(CO)(3)(η(5)-C(5)H(4)(Et)C=C(C(6)H(5))(2)), gives a radical cation which is charge-delocalized between the "cymantrenyl" and diphenylethene moieties and undergoes facile metal-carbonyl substitution reactions. Mn and Re complexes with finely tuned redox potentials can be obtained for cancer cell inhibition studies. |
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