Gold catalyzes the Sonogashira coupling reaction without the requirement of palladium impurities |
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Authors: | Corma Avelino Juárez Raquel Boronat Mercedes Sánchez Félix Iglesias Marta García Hermenegildo |
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Affiliation: | Instituto Universitario de Tecnología Química CSIC-UPV, Universidad Politécnica de Valencia, Av. de los Naranjos, s/n, 46022 Valencia, Spain. acorma@itq.upv.es |
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Abstract: | By a combination of kinetic and theoretical studies it is concluded that gold is intrinsically active to perform the Sonogashira coupling reaction between phenylacetylene and iodobenzene. The presence of Pd impurities is not mandatory for catalyst activity. |
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