Self-induced "electroclick" immobilization of a copper complex onto self-assembled monolayers on a gold electrode |
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| Authors: | Gomila Antoine Le Poul Nicolas Cosquer Nathalie Kerbaol Jean-Michel Noël Jean-Marc Reddy Madhusudana T Jabin Ivan Reinaud Olivia Conan Francoise Le Mest Yves |
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| Affiliation: | Laboratoire de Chimie, Electrochimie Moléculaires et Chimie Analytique, Université de Brest, UMR 6521 CNRS, 29238, Brest, France. |
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| Abstract: | We report the self-induced "electroclick" immobilization of the [Cu(II)(6-ethynyl-TMPA)(H(2)O)](2+) complex, by its simple electro-reduction, onto a mixed azidoundodecane-/decane-thiol modified gold electrode. The redox response of the grafted [Cu(II/I)(TMPA)] at the modified electrode is fully reversible indicating no Cu coordination change and a fast electron transfer. |
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