Enhancement of H2 uptake via fluorination but not lithiation for Zn4N8 and Zn4N6O type clusters |
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| Authors: | Redshaw Carl Jana Surajit Shang Congxiao Elsegood Mark R J Lu Xuesong Guo Zheng Xiao |
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| Institution: | Energy Materials Laboratory, School of Chemistry, The University of East Anglia, Norwich, NR4 7TJ, UK. carl.redshaw@uea.ac.uk |
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| Abstract: | The introduction of fluorinated aryls at zinc in Zn(4)N(8)-type (and to a lesser extent Zn(4)N(6)O) cages led to enhanced H(2) uptake. Lithium alkoxides have been shown to link such cages (non-fluorinated), but showed no substantial improvement in uptake. |
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