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First synthesis of dioxadithiaporphycene with a benzene ring fused onto the double bond
Authors:Wei-Min Dai  Wing Leung Mak
Institution:

Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong SAR, China

Abstract:Dioxadithiaporphycenes 5 and 5′ were synthesized by using the Suzuki cross-coupling and McMurry coupling reactions as the key steps. This approach provided an access to the first dioxadithiaporphycene derivative 15 with a benzene ring fused onto the double bond.
Keywords:porphyrins and analogues  coupling reactions  furans  thiophenes
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