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Thermophysical properties of biodiesel and related systems: (Liquid + liquid) equilibrium data for Jatropha curcas biodiesel
Institution:1. Department of Food Engineering, URI – Campus de Erechim, Erechim, RS 99700-000, Brazil;2. Department of Chemical Engineering, UFSM, Santa Maria, RS 97105-900, Brazil;3. Department of Chemical Engineering, UEM, Maringá, PR 87020 900, Brazil;4. Department of Chemical Engineering, UFPR, Curitiba, PR 81531-990, Brazil;5. Department of Chemical and Food Engineering, UFSC, Florianópolis, SC 88040-900, Brazil;6. Department of Food Technology, IFRS – Campus Sertão, Sertão, RS 99170-000, Brazil;1. Private Centro Vena, Florence, Italy;2. Don Gnocchi Foundation, Florence, Italy;3. Ermini Private Phlebological Office, Grassina, Italy;4. Department of Morphology, Surgery and Experimental Medicine, University of Ferrara, Ferrara, Italy;5. Department of Surgery, Uniformed Services University of the Health Sciences, Bethesda, Md;1. Department of Orthopaedics, Christian Medical College, Vellore, Tamil Nadu, 632004, India;2. Department of Biomedical Engineering, Christian Medical College, Vellore, Tamil Nadu, 632004, India;1. Department of Nephrology, Shandong Provincial Hospital Affiliated to Shandong University, 324 Jingwu Street, Jinan 250021, China;2. Department of Nephrology, Heze Municipal Hospital, Heze, China;1. School of Pharmacy, Nanjing University of Chinese Medicine, Nanjing, Jiangsu, 210023, PR China;2. Jiangsu Key Laboratory for Functional Substance of Chinese Medicine, PR China;3. State Key Laboratory Cultivation Base for TCM Quality and Efficacy, PR China
Abstract:Reported in this study are (liquid + liquid) equilibrium data for binary, ternary, and quaternary systems formed by fatty acid methyl esters (FAME) and fatty acid ethyl esters (FAEE) of Jatropha curcas oil, water, glycerol, methanol, and ethanol at temperatures of (303.15, 318.15, and 333.15) K. In general, all the systems investigated resulted in good agreement between phase compositions of crunodes of tie-lines, solubility curves (binodal curves) and overall compositions, hence indicating low deviations from mass balance. Experimental results were correlated with the UNIQUAC model, showing low deviations among experimental and calculated values.
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