New method for the synthesis of 1,4-enynes by the cross-coupling of magnesium acetylides with allyl compounds |
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Authors: | U M Dzhemilev A G Ibragimov R A Saraev D L Minsker |
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Institution: | (1) Institute of Chemistry, Bashkir Branch, Academy of Sciences of the USSR, Ufa |
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Abstract: | Conclusions A method was developed for the synthesis of 1,4-enynes by the cross-coupling of compounds of type (RC C)2Mg and RC CMgBr with allyl alcohol derivatives using Ni(acac)2-Ph3P as the catalyst.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 907–908, April, 1984. |
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