Polymer-catalyzed hydrolysis of p-nitrophenyl butyrate in an oil/water emulsion |
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| Authors: | I M Okhapkin E E Makhaeva A R Khokhlova |
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| Institution: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991 Moscow, Russian Federation;(2) Department of Physics, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119992 Moscow, Russian Federation |
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| Abstract: | Catalysis of hydrolytic decomposition of p-nitrophenyl butyrate with the copolymer of N-vinylcaprolactam and N-vinylimidazole in an n-dodecane-water emulsion was studied. The reaction rate in the emulsion is higher than that in a solution containing no emulsified
dodecane particles. The data obtained indicate that the reactions involving the surface-active substrate and catalyst can
be accelerated by interfaces.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2109–2111, December, 2006. |
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| Keywords: | N-vinylimidazole hydrolysis emulsion surface reactions |
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