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Synthesis,X-Ray Structure and Characterization of a Triruthenium Cluster Complex Ru_3~Ⅲ(μ_3-O)(μ-CH_3COO)_6(py)_2Cl with Four Steps One-electron Redox Processes
作者姓名:Jing Lin CHEN  Gang Qiang YIN  Zhong Ning CHEN* State Key Laboratory of Structural Chemistry  Fujian Institute of Research on the Structure of Matter  Fuzhou 350002
作者单位:Jing Lin CHEN,Gang Qiang YIN,Zhong Ning CHEN* State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Fuzhou 350002
摘    要:
Great attention is currently paid to the synthesis of polynuclear transition metal complexes as well as their photochemical, photophysical, and electrochemical properties. The design of multicomponent systems capable of performing useful light- and/or redox-induced function is of special interest1. The oxo-centered carboxylate-bridge trinuclear ruthenium clusters have been investigated extensively during recent decades because they have remarkable electron-transfer properties, intense visibl…

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